Goodenough–Kanamori rules

E773254

The Goodenough–Kanamori rules are a set of semi-empirical guidelines that predict the sign and strength of superexchange magnetic interactions between ions in transition-metal oxides based on bond angles and orbital overlap.

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Statements (46)

Predicate Object
instanceOf concept in magnetism ⓘ
semi-empirical guideline ⓘ
theoretical rule in solid-state physics ⓘ
appliesBestTo insulating oxides ⓘ
appliesTo M–O–M superexchange pathways ⓘ
insulating transition-metal compounds ⓘ
transition-metal oxides ⓘ
assumes localized d electrons ⓘ
basedOn bond angle ⓘ
electron occupancy of d orbitals ⓘ
orbital overlap ⓘ
orbital symmetry ⓘ
componentConcept 180-degree superexchange rule ⓘ
90-degree superexchange rule ⓘ
half-filled versus empty or full orbital interactions ⓘ
considers Hund’s rule on the anion ⓘ
Pauli exclusion principle ⓘ
cation–anion–cation geometry ⓘ
overlap between metal d and ligand p orbitals ⓘ
describes magnetic exchange interactions ⓘ
superexchange interactions ⓘ
field condensed matter physics ⓘ
magnetism ⓘ
solid-state chemistry ⓘ
transition-metal oxides ⓘ
hasAbbreviation G–K rules ⓘ
historicalPeriod mid-20th century ⓘ
influences analysis of exchange pathways in complex oxides ⓘ
understanding of perovskite magnetism ⓘ
involves crystal field splitting ⓘ
spin alignment of neighboring ions ⓘ
language English ⓘ
lessAccurateFor itinerant electron systems ⓘ
namedAfter John B. Goodenough ⓘ
Junjiro Kanamori ⓘ
predicts antiferromagnetic coupling ⓘ
ferromagnetic coupling ⓘ
sign of superexchange interaction ⓘ
strength of superexchange interaction ⓘ
relatedTo Goodenough–Kanamori–Anderson rules ⓘ
superexchange theory of Anderson ⓘ
typicalBondAngleCondition 180-degree metal–oxygen–metal bond favors strong superexchange ⓘ
90-degree metal–oxygen–metal bond often leads to weaker or ferromagnetic superexchange ⓘ
usedFor design of magnetic materials ⓘ
interpretation of magnetic structures in oxides ⓘ
qualitative prediction of magnetic ordering ⓘ

How these facts were elicited

Referenced by (4)

Full triples — surface form annotated when it differs from this entity's canonical label.

John B. Goodenough → knownFor → Goodenough–Kanamori rules ⓘ
John B. Goodenough → knownFor → Goodenough–Kanamori rules ⓘ
subject linked to: Goodenough
John B. Goodenough → notableWork → Goodenough–Kanamori–Anderson rules ⓘ
subject linked to: Goodenough
linked to: Goodenough–Kanamori rules
Goodenough–Kanamori rules → relatedTo → Goodenough–Kanamori–Anderson rules ⓘ
linked to: Goodenough–Kanamori rules