Feynman–Hellmann theorem

E1162

The Feynman–Hellmann theorem is a result in quantum mechanics that relates the derivative of an energy eigenvalue with respect to a parameter in the Hamiltonian to the expectation value of the corresponding derivative of the Hamiltonian.

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Generate an image of the Feynman–Hellmann theorem (The Feynman–Hellmann theorem is a result in quantum mechanics that relates the derivative of an energy eigenvalue with respect to a parameter in the Hamiltonian to the expectation value of the corresponding derivative of the Hamiltonian.)

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Statements (41)

Predicate Object
instanceOf quantum mechanics theorem ⓘ
theorem in physics ⓘ
appliesTo Hamiltonians depending on an external parameter ⓘ
Hermitian operators ⓘ
non-degenerate energy eigenstates ⓘ
time-independent Hamiltonians ⓘ
assumes differentiable dependence of the Hamiltonian on the parameter ⓘ
normalized eigenstates of the Hamiltonian ⓘ
category eponymous theorems in physics ⓘ
theorems in quantum mechanics ⓘ
clarifies how changes in Hamiltonian parameters affect observable energies ⓘ
context eigenvalue problems of parameter-dependent operators ⓘ
describes relationship between parameter derivatives of energy eigenvalues and expectation values of Hamiltonian derivatives ⓘ
field quantum mechanics ⓘ
hasGeneralization applications in relativistic quantum field theory ⓘ
extensions to degenerate eigenvalues ⓘ
extensions to multiple parameters ⓘ
mathematicalForm dE_n/dλ = ⟨ψ_n| ∂H/∂λ |ψ_n⟩ ⓘ
namedAfter Hans Hellmann ⓘ
Richard P. Feynman ⓘ
linked to: Richard Feynman
relatedTo Hellmann–Feynman force theorem ⓘ
Rayleigh–Schrödinger perturbation theory ⓘ
variational principle in quantum mechanics ⓘ
relates derivative of an energy eigenvalue with respect to a parameter ⓘ
expectation value of the derivative of the Hamiltonian with respect to that parameter ⓘ
statement For an eigenstate |n(λ)⟩ of H(λ) with eigenvalue E_n(λ), dE_n(λ)/dλ = ⟨n(λ)| ∂H(λ)/∂λ |n(λ)⟩ ⓘ
typeOf eigenvalue perturbation result ⓘ
usedFor calculating parameter dependence of energy levels ⓘ
computing derivatives of bound-state energies with respect to coupling constants ⓘ
computing derivatives of bound-state energies with respect to external fields ⓘ
computing derivatives of bound-state energies with respect to particle masses ⓘ
computing forces in quantum systems ⓘ
computing response of bound-state energies to changes in coupling constants ⓘ
estimating expectation values without explicit wavefunctions ⓘ
perturbation theory in quantum mechanics ⓘ
usedIn atomic physics ⓘ
condensed matter physics ⓘ
lattice quantum chromodynamics ⓘ
molecular physics ⓘ
nuclear physics ⓘ
quantum chemistry ⓘ

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Referenced by (4)

Full triples — surface form annotated when it differs from this entity's canonical label.

Richard Feynman → knownFor → Feynman–Hellmann theorem ⓘ
Feynman–Hellmann theorem → relatedTo → Hellmann–Feynman force theorem ⓘ
linked to: Feynman–Hellmann theorem
Hans Hellmann → notableWork → Feynman–Hellmann theorem ⓘ
Hans Hellmann → notableConcept → Hellmann–Feynman theorem ⓘ
linked to: Feynman–Hellmann theorem