Etter hydrogen-bond rules
E877785
Etter hydrogen-bond rules are a set of guidelines in supramolecular chemistry that systematically describe and predict patterns of hydrogen bonding in molecular and crystal structures.
All labels observed (2)
| Label | Occurrences |
|---|---|
| Etter hydrogen-bond rules canonical | 1 |
| Etter hydrogen-bonding graph-set analysis | 1 |
How this entity was disambiguated
This entity first appeared as the object of triple T10656966 — resolving that mention is where its identity was fixed. The disambiguator weighed these candidate entities and picked the highlighted one (or “None”, minting a new entity). This is how homonymy is resolved: the same surface form can point to different entities.
NED1
Entity disambiguation (via context triple)
gpt-5-mini-2025-08-07
Target entity: Etter hydrogen-bond rules Context triple: [Margaret C. Etter, knownFor, Etter hydrogen-bond rules]
-
A.
The Nature of the Chemical Bond
The Nature of the Chemical Bond is a landmark chemistry book by Linus Pauling that systematically explains chemical bonding using quantum mechanics and became one of the most influential scientific texts of the 20th century.
-
B.
Heitler–London theory of the chemical bond
The Heitler–London theory of the chemical bond is an early quantum mechanical model that explains covalent bonding by treating it as the result of electron exchange and spin pairing between atoms.
-
C.
Hammett acidity function
The Hammett acidity function is a quantitative measure of superacidity in very strong acid solutions, extending the concept of pH to media where conventional acidity scales fail.
-
D.
Longuet-Higgins theorem in molecular symmetry
The Longuet-Higgins theorem in molecular symmetry is a fundamental result in theoretical chemistry that relates molecular symmetry properties to electronic state degeneracies and the occurrence of phenomena such as the Jahn–Teller effect.
-
E.
Westheimer rules in physical organic chemistry
Westheimer rules in physical organic chemistry are empirical guidelines that relate molecular structure and substituent effects to reaction rates and mechanisms, helping to rationalize and predict reactivity patterns.
- F. None of above. chosen
- G. Unsure - the case is ambiguous/there is not enough information to decide.
NED2
Entity disambiguation (via description)
gpt-5-mini-2025-08-07
Target entity: Etter hydrogen-bond rules Target entity description: Etter hydrogen-bond rules are a set of guidelines in supramolecular chemistry that systematically describe and predict patterns of hydrogen bonding in molecular and crystal structures.
-
A.
The Nature of the Chemical Bond
The Nature of the Chemical Bond is a landmark chemistry book by Linus Pauling that systematically explains chemical bonding using quantum mechanics and became one of the most influential scientific texts of the 20th century.
-
B.
Heitler–London theory of the chemical bond
The Heitler–London theory of the chemical bond is an early quantum mechanical model that explains covalent bonding by treating it as the result of electron exchange and spin pairing between atoms.
-
C.
Hammett acidity function
The Hammett acidity function is a quantitative measure of superacidity in very strong acid solutions, extending the concept of pH to media where conventional acidity scales fail.
-
D.
Longuet-Higgins theorem in molecular symmetry
The Longuet-Higgins theorem in molecular symmetry is a fundamental result in theoretical chemistry that relates molecular symmetry properties to electronic state degeneracies and the occurrence of phenomena such as the Jahn–Teller effect.
-
E.
Westheimer rules in physical organic chemistry
Westheimer rules in physical organic chemistry are empirical guidelines that relate molecular structure and substituent effects to reaction rates and mechanisms, helping to rationalize and predict reactivity patterns.
- F. None of above. chosen
Statements (44)
| Predicate | Object |
|---|---|
| instanceOf |
concept in supramolecular chemistry
ⓘ
model for hydrogen-bond patterns ⓘ set of empirical rules ⓘ |
| appliesTo |
crystal structures
ⓘ
hydrogen bonding ⓘ molecular structures ⓘ |
| assumes |
hydrogen bonds form whenever suitable donors and acceptors are present
ⓘ
intramolecular hydrogen bonds form in preference to intermolecular ones when possible ⓘ strong donors form hydrogen bonds to best available acceptors ⓘ |
| basedOn | donor–acceptor concept ⓘ |
| characteristic |
empirical
ⓘ
pattern-based ⓘ qualitative ⓘ |
| concerns |
graph-set notation
ⓘ
hydrogen-bond acceptors ⓘ hydrogen-bond donors ⓘ hydrogen-bond synthons ⓘ |
| describedIn | crystallographic literature ⓘ |
| field |
crystal engineering
ⓘ
crystallography ⓘ supramolecular chemistry ⓘ |
| influenced |
development of crystal engineering strategies
ⓘ
systematic study of hydrogen-bond motifs ⓘ |
| involves |
classification of hydrogen-bond patterns
ⓘ
recognition of recurring supramolecular synthons ⓘ |
| namedAfter | Margaret C. Etter ⓘ |
| purpose |
describe hydrogen-bond patterns
ⓘ
predict hydrogen-bond patterns ⓘ systematize hydrogen-bonding in crystals ⓘ |
| relatedConcept |
graph-set analysis of hydrogen bonds
ⓘ
hydrogen-bond topology ⓘ supramolecular synthon concept ⓘ |
| relatesTo |
competition between hydrogen bonds
ⓘ
hierarchy of hydrogen-bond strengths ⓘ preferred hydrogen-bond motifs ⓘ |
| timePeriod | late 20th century ⓘ |
| usedBy |
crystal engineers
ⓘ
crystallographers ⓘ supramolecular chemists ⓘ |
| usedIn |
analysis of hydrogen-bond networks
ⓘ
co-crystal design ⓘ design of crystal packing ⓘ design of supramolecular assemblies ⓘ pharmaceutical crystal engineering ⓘ |
How these facts were elicited
The pipeline generated the facts above by prompting gpt-5.1 with this entity's name + description and the instruction below.
Instruction
You are a knowledge base construction expert. Given a subject entity and a description of it, return factual statements that you know for the subject as a JSON list of dictionaries(triples), where keys must be "subject", "predicate" and "object". The number of facts may be very high, between 25 to 50 or more, for very popular subjects. For less popular subjects, the number of facts can be very low, like 5 or 10. # Requirements - If you don't know the subject at all, return an empty list. - If the subject is not a named entity, return an empty list. - Include at least one triple where predicate is "instanceOf". - Do not get too wordy. - Separate several objects into multiple triples with one object.
Input
Subject: Etter hydrogen-bond rules Description of subject: Etter hydrogen-bond rules are a set of guidelines in supramolecular chemistry that systematically describe and predict patterns of hydrogen bonding in molecular and crystal structures.
Referenced by (2)
Full triples — surface form annotated when it differs from this entity's canonical label.
subject linked to:
Etter
linked to: Etter hydrogen-bond rules