Hammett acidity function

E743330

The Hammett acidity function is a quantitative measure of superacidity in very strong acid solutions, extending the concept of pH to media where conventional acidity scales fail.

All labels observed (1)

Label Occurrences
Hammett acidity function canonical 3

How this entity was disambiguated

Statements (46)

Predicate Object
instanceOf acidity function ⓘ
acidity scale ⓘ
chemical concept ⓘ
abbreviation H0 ⓘ
appliesTo concentrated sulfuric acid ⓘ
fluoroantimonic acid ⓘ
magic acid ⓘ
non‑aqueous strongly acidic media ⓘ
superacid solutions ⓘ
assumes common activity coefficient for indicator base forms ⓘ
basedOn equilibrium of weak bases in acid media ⓘ
indicator base ionization equilibria ⓘ
category acid–base property scale ⓘ
thermodynamic acidity measure ⓘ
contrastsWith activity‑based pH definition ⓘ
convention more negative H0 indicates stronger acidity ⓘ
dependsOn concentration of protonated base ⓘ
concentration of unprotonated base ⓘ
pKBH+ of indicator base ⓘ
developedBy Louis Plack Hammett ⓘ
linked to: Louis P. Hammett
developedIn 1930s ⓘ
extends pH concept ⓘ
field acid–base chemistry ⓘ
physical organic chemistry ⓘ
hasFormula H0 = pKBH+ + log([B]/[BH+]) ⓘ
hasLimitation depends on choice of indicator base ⓘ
may differ between different basic indicators in same medium ⓘ
measures acidity in very strong acid solutions ⓘ
superacidity ⓘ
namedAfter Louis Plack Hammett ⓘ
linked to: Louis P. Hammett
relatedTo Brønsted acidity ⓘ
Lewis acidity ⓘ
acidity function H− ⓘ
pH scale ⓘ
requires series of indicator bases with known pKBH+ ⓘ
unit dimensionless ⓘ
usedBy catalysis researchers ⓘ
physical organic chemists ⓘ
synthetic organic chemists ⓘ
usedFor characterizing acidity where pH is not defined ⓘ
comparing strengths of superacids ⓘ
quantifying protonating ability of superacids ⓘ
usedIn carbocation chemistry ⓘ
electrophilic substitution studies ⓘ
industrial superacid catalysis research ⓘ
kinetic studies in superacid media ⓘ

How these facts were elicited

Referenced by (3)

Full triples — surface form annotated when it differs from this entity's canonical label.

Louis P. Hammett → knownFor → Hammett acidity function ⓘ
Louis P. Hammett → developed → Hammett acidity function ⓘ
Superacids → topic → Hammett acidity function ⓘ
subject linked to: “Superacids”