Ehrenfest model

E735840

The Ehrenfest model is a classic probabilistic model in statistical mechanics that illustrates the approach to equilibrium and fluctuations in a gas by tracking particles randomly moving between two containers.

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Ehrenfest model canonical 2

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Statements (49)

Predicate Object
instanceOf Markov chain ⓘ
model in statistical mechanics ⓘ
probabilistic model ⓘ
urn model ⓘ
alsoKnownAs Ehrenfest urn model ⓘ
demonstrates law of large numbers behavior for large N ⓘ
typicality of equilibrium macrostate ⓘ
describes random motion of particles between two containers ⓘ
equilibriumDistribution binomial distribution ⓘ
equilibriumProperty satisfies detailed balance ⓘ
field probability theory ⓘ
statistical mechanics ⓘ
stochastic processes ⓘ
hasComponent N indistinguishable particles ⓘ
two urns ⓘ
hasParameter number of particles N ⓘ
hasProperty aperiodic ⓘ
ergodic ⓘ
irreducible ⓘ
time-homogeneous ⓘ
illustratesConcept Boltzmann’s H-theorem ⓘ
linked to: H-theorem

fluctuations around equilibrium ⓘ
macroscopic irreversibility from microscopic reversibility ⓘ
recurrence ⓘ
mathematicalTool Markov chain theory ⓘ
linked to: Markov processes

binomial coefficients ⓘ
stochastic convergence ⓘ
models approach to thermodynamic equilibrium ⓘ
namedAfter Paul Ehrenfest ⓘ
Tatiana Ehrenfest ⓘ
originalContext kinetic theory of gases ⓘ
purpose illustrate approach to equilibrium ⓘ
illustrate fluctuations in a gas ⓘ
relatedTo Boltzmann equation ⓘ
birth–death process ⓘ
random walk on the hypercube ⓘ
stateSpace number of particles in one urn ⓘ
stateSpaceType finite ⓘ
timeReversalProperty microscopically reversible ⓘ
transitionGraph birth–death chain ⓘ
transitionRule at each step one particle is chosen at random and moved to the other urn ⓘ
transitionType discrete-time ⓘ
typicalAssumption all particles are equally likely to be chosen ⓘ
particles are non-interacting ⓘ
usedIn studies of mixing times ⓘ
studies of relaxation to equilibrium ⓘ
teaching Markov chains ⓘ
teaching statistical mechanics ⓘ
yearProposed 1907 ⓘ

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Referenced by (2)

Full triples — surface form annotated when it differs from this entity's canonical label.

Paul Ehrenfest → notableWork → Ehrenfest model ⓘ
Paul Ehrenfest → notableConcept → Ehrenfest model ⓘ
subject linked to: Ehrenfest