Jablonski diagram
E620789
A Jablonski diagram is a graphical representation of the electronic energy levels of a molecule and the radiative and non-radiative transitions between them, commonly used to illustrate fluorescence, phosphorescence, and related photophysical processes.
All labels observed (1)
| Label | Occurrences |
|---|---|
| Jablonski diagram canonical | 2 |
How this entity was disambiguated
This entity first appeared as the object of triple T6788461 — resolving that mention is where its identity was fixed. The disambiguator weighed these candidate entities and picked the highlighted one (or “None”, minting a new entity). This is how homonymy is resolved: the same surface form can point to different entities.
NED1
Entity disambiguation (via context triple)
gpt-5-mini-2025-08-07
Target entity: Jablonski diagram Context triple: [Stokes shift, relatedTo, Jablonski diagram]
-
A.
Franck–Condon principle
The Franck–Condon principle is a rule in molecular spectroscopy that explains the intensity distribution of vibronic transitions by assuming electronic transitions occur much faster than nuclear motion, making vertical transitions between vibrational states most probable.
-
B.
Huang–Rhys factor
The Huang–Rhys factor is a dimensionless parameter in solid-state and molecular spectroscopy that quantifies the strength of electron–phonon (vibronic) coupling during electronic transitions.
-
C.
Stokes shift
Stokes shift is a phenomenon in spectroscopy where the wavelength of emitted light is longer (lower energy) than that of the absorbed light, commonly observed in fluorescence and phosphorescence.
-
D.
Herzberg–Teller approximation
The Herzberg–Teller approximation is a refinement in molecular spectroscopy that accounts for vibronic coupling by allowing electronic transition dipole moments to depend on nuclear coordinates, explaining intensity in otherwise forbidden transitions.
-
E.
Feynman diagrams
Feynman diagrams are graphical representations used in quantum field theory to visualize and calculate particle interactions and processes.
- F. None of above. chosen
- G. Unsure - the case is ambiguous/there is not enough information to decide.
NED2
Entity disambiguation (via description)
gpt-5-mini-2025-08-07
Target entity: Jablonski diagram Target entity description: A Jablonski diagram is a graphical representation of the electronic energy levels of a molecule and the radiative and non-radiative transitions between them, commonly used to illustrate fluorescence, phosphorescence, and related photophysical processes.
-
A.
Franck–Condon principle
The Franck–Condon principle is a rule in molecular spectroscopy that explains the intensity distribution of vibronic transitions by assuming electronic transitions occur much faster than nuclear motion, making vertical transitions between vibrational states most probable.
-
B.
Huang–Rhys factor
The Huang–Rhys factor is a dimensionless parameter in solid-state and molecular spectroscopy that quantifies the strength of electron–phonon (vibronic) coupling during electronic transitions.
-
C.
Stokes shift
Stokes shift is a phenomenon in spectroscopy where the wavelength of emitted light is longer (lower energy) than that of the absorbed light, commonly observed in fluorescence and phosphorescence.
-
D.
Herzberg–Teller approximation
The Herzberg–Teller approximation is a refinement in molecular spectroscopy that accounts for vibronic coupling by allowing electronic transition dipole moments to depend on nuclear coordinates, explaining intensity in otherwise forbidden transitions.
-
E.
Feynman diagrams
Feynman diagrams are graphical representations used in quantum field theory to visualize and calculate particle interactions and processes.
- F. None of above. chosen
Statements (48)
| Predicate | Object |
|---|---|
| instanceOf |
graphical representation
ⓘ
scientific diagram ⓘ |
| appliesTo |
atoms
ⓘ
molecules ⓘ solids with discrete energy levels ⓘ |
| axis |
horizontal configuration coordinate or reaction coordinate
ⓘ
vertical energy axis ⓘ |
| clarifies |
difference between fluorescence and phosphorescence
ⓘ
radiative and non-radiative decay pathways ⓘ spin-allowed and spin-forbidden transitions ⓘ |
| field |
molecular spectroscopy
ⓘ
photochemistry ⓘ photophysics ⓘ |
| helpsAnalyze |
fluorescence lifetime
ⓘ
photobleaching processes ⓘ quantum yield of fluorescence ⓘ |
| namedAfter | Alexander Jablonski ⓘ |
| relatedTo |
energy level diagram
ⓘ
state diagram ⓘ |
| represents |
electronic energy levels of a molecule
ⓘ
non-radiative transitions ⓘ radiative transitions ⓘ |
| shows |
absorption transitions
ⓘ
excited singlet states ⓘ excited triplet states ⓘ fluorescence emission ⓘ ground electronic state ⓘ internal conversion transitions ⓘ intersystem crossing transitions ⓘ non-radiative relaxation ⓘ phosphorescence emission ⓘ vibrational relaxation ⓘ vibrational sublevels ⓘ |
| usedFor |
explaining excited-state dynamics
ⓘ
illustrating fluorescence ⓘ illustrating internal conversion ⓘ illustrating intersystem crossing ⓘ illustrating phosphorescence ⓘ teaching photophysical processes ⓘ visualizing energy relaxation pathways ⓘ |
| usedIn |
design of fluorescent probes
ⓘ
fluorescence spectroscopy ⓘ laser physics education ⓘ time-resolved spectroscopy ⓘ |
| usesNotation |
straight arrows for radiative processes
ⓘ
wavy arrows for non-radiative processes ⓘ |
| visualStyle |
arrows connecting energy levels to indicate transitions
ⓘ
discrete horizontal lines for energy levels ⓘ |
How these facts were elicited
The pipeline generated the facts above by prompting gpt-5.1 with this entity's name + description and the instruction below.
Instruction
You are a knowledge base construction expert. Given a subject entity and a description of it, return factual statements that you know for the subject as a JSON list of dictionaries(triples), where keys must be "subject", "predicate" and "object". The number of facts may be very high, between 25 to 50 or more, for very popular subjects. For less popular subjects, the number of facts can be very low, like 5 or 10. # Requirements - If you don't know the subject at all, return an empty list. - If the subject is not a named entity, return an empty list. - Include at least one triple where predicate is "instanceOf". - Do not get too wordy. - Separate several objects into multiple triples with one object.
Input
Subject: Jablonski diagram Description of subject: A Jablonski diagram is a graphical representation of the electronic energy levels of a molecule and the radiative and non-radiative transitions between them, commonly used to illustrate fluorescence, phosphorescence, and related photophysical processes.
Referenced by (2)
Full triples — surface form annotated when it differs from this entity's canonical label.
subject linked to:
Jabłoński