Fischer projection

E180490

The Fischer projection is a two-dimensional representation used in organic chemistry to depict the three-dimensional stereochemistry of molecules, especially carbohydrates and amino acids.

All labels observed (1)

Label Occurrences
Fischer projection canonical 2

How this entity was disambiguated

Statements (48)

Predicate Object
instanceOf chemical notation ⓘ
stereochemical projection ⓘ
two-dimensional representation ⓘ
appliesTo open-chain forms of sugars ⓘ
tetrahedral stereocenters ⓘ
category chemical drawing convention ⓘ
stereochemical representation system ⓘ
developedBy Emil Fischer ⓘ
developedFor systematic representation of sugar stereochemistry ⓘ
field organic chemistry ⓘ
hasConstraint cannot be freely rotated in the plane without changing configuration meaning ⓘ
not suitable for representing cyclic conformations accurately ⓘ
rotation by 180 degrees in the plane preserves configuration ⓘ
rotation by 90 degrees in the plane inverts stereochemistry ⓘ
hasConvention D and L notation is based on orientation of substituents around the reference carbon ⓘ
horizontal substituents are considered toward the observer ⓘ
vertical substituents are considered away from the observer ⓘ
hasFeature assumes viewer is in front of the plane of the paper ⓘ
carbon chain is drawn vertically ⓘ
chiral centers are represented at line intersections ⓘ
does not explicitly show wedge and dash bonds ⓘ
horizontal lines represent bonds coming out toward the viewer ⓘ
most oxidized carbon is placed at the top ⓘ
uses cross-like representation for tetrahedral centers ⓘ
vertical lines represent bonds going away from the viewer ⓘ
namedAfter Emil Fischer ⓘ
relatedTo Haworth projection ⓘ
Newman projection ⓘ
linked to: sawhorse projection

sawhorse projection ⓘ
wedge-and-dash notation ⓘ
timePeriod late 19th century ⓘ
usedFor assigning R and S configuration ⓘ
comparing stereoisomers ⓘ
depicting three-dimensional stereochemistry ⓘ
distinguishing diastereomers ⓘ
distinguishing enantiomers ⓘ
drawing aldoses ⓘ
drawing ketoses ⓘ
drawing monosaccharides ⓘ
representing amino acids ⓘ
representing carbohydrates ⓘ
representing chiral centers ⓘ
usedIn biochemistry ⓘ
carbohydrate chemistry ⓘ
configuration assignment of D and L sugars ⓘ
configuration assignment of amino acids ⓘ
stereochemistry education ⓘ
textbook representations of sugars ⓘ

How these facts were elicited

Referenced by (2)

Full triples — surface form annotated when it differs from this entity's canonical label.

Emil Fischer → knownFor → Fischer projection ⓘ
sawhorse projection → comparedWith → Fischer projection ⓘ